Amy: Purchase her in the Character Creation for 4,000 gold.
Angol Fear: Defeat Angol Fear in Story mode with Algol, Kilik, Scheherazade, The Apprentice, or Zasalamel.
Ashlotte: Defeat Ashlotte in Story mode with Angol Fear, Astaroth, Lizardman, Maxi, Rock, or Talim.
Cervantes: Purchase him in the Character Creation for 4,000 gold.
Hong Yun-seong: Purchase him in the Character Creation for 4,000 gold.
Kamikirimusi: Defeat Kamikirimusi in Story mode. Note: Mitsurugi is one of the characters that encounters Kamikirimusi in his story.
Lizardman: Purchase him in the Character Creation for 4,000 gold.
Rock: Purchase him in the Character Creation for 4,000 gold.
Scheherazade: Defeat Scheherazade in Story mode with Nightmare, Siegfried, Voldo, Yoda, or Yoshimitsu.
Seong Mi Na: Purchase her in the Character Creation for 4,000 gold.
Setsuka: Purchase her in the Character Creation for 4,000 gold.
Shura: Defeat Shura in Story mode with Cervantes, Rapahel, Setsuka, or Taki.
Sophitia: Purchase her in the Character Creation for 4,000 gold.
Talim: Purchase her in the Character Creation for 4,000 gold.
The Apprentice: Successfully complete Arcade mode with Yoda.
Yoshimitsu: Purchase him in the Character Creation for 4,000 gold.
Zasalamel: Purchase him in the Character Creation for 4,000 gold.